The structure of unsolvated neopentyl sodium has been reported in Angewandte Chemie (🔎 https://ccdc-info.com/4lmqyrL), revealing a rare tetrameric motif. When combined with N,N,N',N'',N''-pentamethyldiethylenetriamine, it allows for the direct metalation of challenging non-activated arenes and alkenes. 🔗 CSD Entry SAGDEO: https://ccdc-info.com/4m42f35 #FeaturedStructureFriday #Crystallography | Cambridge Crystallographic Data Centre (CCDC)
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The structure of unsolvated neopentyl sodium has been report…
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SOLVED:(a) Draw the structures of ethyl, n-propy1, isobutyl, and neopentyl bromides. These structures can be considered methyl bromide with one of its hydrogens replaced by various alky1 groups (GGH2 Br). What is the group G in each case? (b) The relative rates of reaction (with ethoxide ion) are roughly: methyl bromide, 100 ; ethyl bromide, 6 ; n -propyl bromide, 2 ; isobutyl bromide, 0.2 ; neopentyl bromide, 0.00002. What is the effect of the size of the group G attached to carbon bearing the
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